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Moreover, Pb-bearing minerals mostly remained undissolved, but approximately 30% Pb was immobilized by secondary Fe-rich minerals. The present findings revealed the critical role of exogenous Acidithiobacillus species in accelerating the precursory process of mineral weathering and secondary mineral formation for hardpan structure development in sulfidic Pb-Zn tailings.Organic pollutants, with their increasing concentrations in the ambient air, are posing a severe threat to human health. Metal-organic frameworks (MOFs), due to their act