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The permselectivity of the polyaniline-modified perfluorinated membrane to H+ in the mixture of H+/Ca2+ cations is observed in all current regimes.The prominence of spider silk as a hallmark in biomimetics relies not only on its unrivalled mechanical properties, but also on how these properties are the result of a set of original design principles. In this sense, the study of spider silk summarizes most of the main topics relevant to the field and, consequently, offers a nice example on how these topics could be considered in other biomim