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As typical 2D materials, VSe2 and MoSe2 both play a complementary role in Li/Na/K storage. Therefore, we designed and optimized the VSe2/MoSe2 heterostructure to gain highly efficient Li/Na/K-ion batteries. Most importantly, achieving fast Li/Na/K-ion diffusion kinetics in the interlayer of VSe2/MoSe2 is a key point. First of all, first-principles calculations were carried out to systematically investigate the packing structure, mechanical properties, band structure, and Li/Na/K storage mechanism. Our calculated results suggest that a la