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We propose a pump-probe time-resolved infrared spectroscopy study to verify the mechanism. These findings can clarify the ongoing dispute over the understanding of the high TADF quantum efficiency for two-coordinate metal complexes.The exploration of two-dimensional (2D) semiconductors with intrinsic room-temperature magnetism for use in nanoscale spintronic devices is of particular interest. Recently, the ferromagnetic CrX3 monolayer (X = Br, I) has received growing attention, but low critical temperature hinders its practical applicati