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The oxyhalide-induced oxidation of Cr(III) in frozen answer showed an alternate trend from that in aqueous option. Cr(VI) production had been greater in frozen than aqueous solution with hypochlorous acid (HOCl) and bromate (BrO3-) but suppressed in frozen answer with hypobromous acid (HOBr) and periodate (IO4-). In particular, bromate markedly enhanced Cr(VI) manufacturing in frozen solution, whereas it had a negligible task in aqueous answer. On the contrary, periodate