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Secondly, we characterize in detail the normal modes of vibration of the reactants. In , reaction rates were modified only when specific vibrations of the reactants were coupled to a cavity mode. #link# We find that these vibrations are highly mixed among the different fragments of the reactants leading to a completely new assignment of the IR peaks coupled to cavity modes in the original experimental works. Our results are fundamental for the interpretation of the VSC experiments given that in the absence of a theory explaining these
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