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Two physical properties in polymers, hydrophobic and water-absorptive, are known to be incompatible. However, human skin in nature has a hydrophobic surface and yet absorbs water throughout hydrophilic amino acid sequences in filaggrin, one of the abundant proteins in our outermost skin layer. Although present in nature, a hydrophilic path network in a hydrophobic polymer is difficult to synthesize because of poor wettability and immiscibility between the two types of materials. Herein, we introduce a novel method for the creation of a hyd