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This plan could supply a straightforward approach to access atropisomeric anilides, very difficult types of axially chiral substances.We demonstrate a facile discerning synthesis of phase-pure anatase, rutile, and brookite nanocrystal polymorphs of titania (TiO2) using a benign hydrothermal treatment of an industrial grade TiOSO4 precursor. Acetic acid (CH3COOH) can be used for the synthesis of anatase, glycolic acid (HOCH2COOH) is used for rutile, and both glycolic acid and ammonium hydr