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Cellulose saccharification to produce glucose is considered as an important approach for application of biomass resources. Solid acids as catalysts for this purpose have attracted much attention with the advantages of environmental friendliness, easy separation of products, and recyclability. In this work, a new method was introduced to prepare a H3PO4-based solid acid catalyst by simply grinding with kaolinite. Characterizations of the prepared products based on a set of analytical methods as well as cellulose hydrolysis were investigated