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This research provides a novel hint for fabricating visible-light-responsive heterojunction photocatalysts with high performance for energy production.We have fabricated Ag-Au alloy nanocubes using the galvanic replacement of silver nanocubes by aqueous HAuCl4 and investigated their morphological, structural, compositional and optical properties. The inter-diffusion between silver and gold at 100 °C leads to the formation of Ag-Au alloy nanocubes with hollow interiors. A broad tuning of the surface plasmon resonance (SPR) wavelength fro