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This paper reports for the first time the occurrence, fates, and carcinogenic risks of 20 substituted polycyclic aromatic hydrocarbons (SPAHs) and 16 priority PAH species in two coking wastewater treatment plants (WWTPs) (plant E and central WWTP). The measured total concentrations of PAHs and SPAHs in raw wastewater of coking plant E were 3700 and 1200 μg·L-1, respectively, with naphthalene (1400 μg·L-1), and fluoranthene (353 μg·L-1) as dominant PAH species and 2-methylnaphthalene (167 μg·L-1), anthraquinone (133 μg·L-1), and 1-methyl
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