https://lorlatinibinhibitor.co....m/study-of-permittiv
Right here we report the synthesis and (chir)optical properties of a chiral benzo[b]silole-fused 9,9'-spirobi[fluorene] (SBF) and π-extended spiro polycyclic arene. The benzo[b]silole-fused SBF had been successfully synthesized by a rhodium-catalyzed intramolecular silylative cyclization. It had been more transformed to the chiral π-extended spiro polycyclic arene by an annulative π-extension reaction. Less effective spiroconjugation had been seen for these spi